Rationale
The composition of ground water reflects the influence parameters
such as bedrock, Quaternary deposit and soil composition, ground
water flow paths and velocity, etc. have upon the water that infiltrates
the ground. Ground water in much of the temperate and cool areas
of northern Europe is a significant component of stream water,
and, as such, can help interpret the surface water data.
Advantages
Allows the geogenic contribution to solutes in a catchment (weathering)
to be constrained.
Drawbacks
Expensive and complicated medium to sample and analyse (except
at springs) (Figs. 1-2).
Seasonal variations require monitoring.
Common very low concentration levels impose non-contaminating
equipment and procedures, as well as extremely low detection limits
on analytical instruments (or pre-concentration methods).